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Application of Vermiculite Boards in Electrolytic Aluminum Cells

As a high-performance corrosion-resistant insulation board, vermiculite boards primarily serve as thermal insulation and anti-seepage buffer layers in electrolytic aluminum cells. They are suitable for sealing cell bottoms, side walls, and joints, significantly reducing heat dissipation and power consumption, inhibiting electrolyte permeation, and extending cell lifespan.

Applications and Functions of Vermiculite Boards in Electrolytic Aluminum Cells:
Cell Bottom Insulation / Leak Prevention: Placed beneath cathode carbon blocks to reduce downward heat transfer and fluoride corrosion, stabilizing pressure drop at the cell base.
Sidewall Insulation: Adhered to inner or outer tank surfaces to lower surface temperatures and minimize heat loss.
Seam/Joint Sealing: Fills gaps around tank joints and openings to prevent air ingress and electrolyte leakage.
Structural Support & Thermal Shock Resistance: Provides cushioning during rapid temperature shifts at startup/shutdown, maintaining insulation integrity.


Application of Vermiculite Boards in Electrolytic Aluminum Cells


Key Properties and Parameters of Vermiculite Boards:
High-Temperature Resistance: Melting point approx. 1370–1400°C, maximum operating temperature approx. 1200°C, suitable for electrolytic cell operating conditions of 950–970°C.
Thermal Insulation: Thermal conductivity approximately 0.04–0.13 W/(m·K), typically around 0.04–0.06 W/(m·K).
Corrosion Resistance / Permeation Barrier: Inhibits permeation of cryolite-alumina molten salts and fluoride compounds.
Mechanical & Safety: Compressive strength: 0.3–10 MPa; Density: 500–1200 kg/m³; Non-combustible (Class A), non-toxic.

Performance of Vermiculite Boards in Electrolytic Aluminum Cell Projects (Excerpts):
A 500 kA series cell with an 80 mm vermiculite insulation layer achieved a cell voltage drop reduction of approximately 30 mV and a decrease in DC power consumption per ton of aluminum by about 100 kWh.
Vermiculite anti-seepage bricks installed beneath cathode carbon blocks in a 500 kA cell significantly reduced furnace bottom pressure drop and extended service life.

Key Selection and Installation Guidelines for Vermiculite Boards:
Thickness and Density: Typically 50–100 mm for cell bottoms/side walls; prioritize densities of 600–1000 kg/m³ for balanced thermal insulation and strength.
Composite Structure: Inner refractory bricks/castables resist erosion, intermediate vermiculite panels provide insulation, outer layer sealed or steel-plated.
Installation and Sealing:
Offset joints with high-temperature sealant/mortar filling; reinforce edges, corners, and openings to prevent thermal bridges.
Hot-State Anchoring:
Use high-temperature anchors in zones ≥600°C to prevent displacement or detachment.
Quality Control:
Spot-check density, compressive strength, thermal conductivity, and flexural strength; verify flatness and joint integrity during installation.